![]() Freeze was arrested and placed into a sub-zero holding cell (7021059), in Arkham Asylum. Batman handed over the video security footage to the Gotham Police, which presented evidence that led to Boyle being exposed for misdeeds involving Nora. However, Batman had defeated Freeze by using a thermos of chicken soup at the spur of the moment to crack Freeze's helmet, thus raising his body temperature and rendered him unconscious. Freeze managed to trap Boyle in ice that was caked up to the waist when Batman tackled him and the fight ensued. Freeze intended to kill Boyle in revenge at a party where GothCorp's CEO was due to earn the "Gotham Humanitarian of the Year" Award, but Batman foiled it on account of Freeze putting innocent civilians in danger in his quest for vengeance. He first attacked GothCorp, although his plan was stopped by Batman managing to capture one of Freeze's underlings. ![]() Revenge ĭriven by hatred over the destruction of his life and maddened by his condition, Mr. ![]() Freeze" as he created a vacuum tight suit which maintained his body temperature at 50 degrees below zero and tripled his strength and a laser-powered cold gun. Vowing revenge on those who had wronged him, he was known as "Mr. The resulting explosion smashed him into his cryogenic freezing tanks and the accident soaked his entire body with the freezing solution and rendered him unable to survive outside of a sub-zero environment. Boyle's smooth talk got to Fries as he relaxed and let down his guard, allowing the deceitful CEO to kick the scientist into a lab table full of beakers which exploded. Fries was then calmly ordered by Boyle to drop the gun, reasoning that it was not his nature to resort to violence and that a possibility may have existed to legitimately bankroll Nora's experiment. Fries was interrupted by GothCorp's CEO Ferris Boyle and a fight ensued and Fries grabbed a handgun, pointing it at Boyle and the security guards. However, Fries had been misappropriating GothCorp's money, which left the company in debt and the experiment unauthorized. When Nora was infected with a deadly disease, he developed a special freezing cell and planned to cryogenically hold until a cure was found. ![]() Victor Fries was the husband of Nora Fries and one of GothCorp's most brilliant scientists and cryogenic researchers. ![]()
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![]() ![]() Also femininity does not equal weakness?!!! Omg?! Insane right? Who knew? And also totally unheard of and insane to want to express yourself differently at different times.” These marked Eilish's bluntest and most straightforward comments this year regarding the public's perception of her. 104, 942 Live PerformancesTelevised performances, tours, festivals etc. The 20-year-old tops the bill just three years after her Glastonbury debut at a jam. LET WOMEN EXIST!”Įilish added, “Did you know women are multifaceted!!!!!? Shocking right? Believe it or not, women can be interested in multiple things. Candids AppareancesPhotographs of Billie Eilish captured by paparazzi, or fans. Billie Eilish will become Glastonburys youngest ever solo headliner when she plays the Pyramid Stage on Friday. ![]() Party Six: Jeremy Strong, Anne Hathaway, and Jon Neidich at The Nines. oMG iT's nOt thE sAmE biLlie she's just like the rest, bla blah. That is an amazing photo of Billie Eilish. “And now when I feel comfortable enough to wear anything remotely feminine or fitting, I CHANGED and am a sellout.and ‘what happened to her. The global star has announced her Happier Than Ever, The World Tour dates. I spent the first five years of my career getting absolutely OBLITERATED by you fools for being boyish and dressing how I did and constantly being told I'd be hotter if I acted like a woman. BBillie Eilish fans are going to be happier than ever in 2022. She wrote on a series of Instagram Stories in late May, “Letter to some comments I be seeing sometimes. Midway through a world tour that sees her singing to packed stadiums, Billie Eilish sticks to a nighttime beauty routine both for the sake of her skin and he. Fans can’t hold their reactions over the trending video and many have agreed that Tobey being Billie’s fan is the multiverse we all need. The lone teardrop isn’t obvious at first, shiny enough that it could just be part of her glittery makeup. The singer recently hit back at commenters accusing her of “selling out” because she is wearing more feminine clothes. Billie Eilish is crying on the cover of her new album. Eilish hasn't often posted in swimwear on Instagram. ![]() ![]() ![]() Adding a heat will convert the solid into a liquid with no temperature change. ![]() The melting point also defines a condition in which the solid and liquid can exist in equilibrium. The melting point of a substance is the temperature at which this phase change occurs. In general, melting is a phase change of a substance from the solid to the liquid phase. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. In the periodic table of elements, the element with the lowest boiling point is helium. On the other hand, water boils at 350☌ (662☏) at 16.5 MPa (typical pressure of PWRs). A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.Īs can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Any addition of thermal energy results in a phase transition. The liquid can be said to be saturated with thermal energy. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. In general, boiling is a phase change of a substance from the liquid to the gas phase. Note that, these points are associated with the standard atmospheric pressure. Irritation: Niobium dust causes eyes and skin irritation.Thermal Properties of Niobium Niobium – Melting Point and Boiling Point Medicine: Niobium is physiologically inert and hypoallergenic, meaning that it is an allergen to very few, for this reason it is used to make prosthetic arm.Superconducting Magnets: Niobium-germanium, niobium-tin, and niobium-titanium alloys are used as superconductor wires to make magnets which finds its use in MRI machines, NMR Spectroscopes, Large Hadron Collider (LHC) etc.Niobium is used in iron, cobalt, nickel based superalloys. Superalloys: This constitutes second largest use of the total niobium production.Niobium is sometimes used in very high quantity to produce highly wear and tear resistant machine elements. It is used for grain sizing, to retard recrystallization, and precipitation hardening. Steel industry: About 90% of the total niobium production is used in steel industries.Relevance in Chemical and Related Industries The same reaction without iron oxide is used to produce niobium metal directly but further processing has to be done to improve the grade. The products formed are aluminium oxide and ferroniobium, which is of industrial importance. Small amounts of sodium nitrate is added to enhance the reaction. Aluminothermic reaction: A mixture of aluminium oxide and niobium oxide is reacted with aluminium.This is reduced to obtain niobium in high purity. To obtain Niobium, first the ore is subjected to leaching using organic solvents then water is used to extract and then potassium fluoride is added to form a potassium fluoride complex. Extraction & Reduction: Mostly tantalum and niobium occur together in ores thus they are processed together and separated to obtain the element of desire.Niobium is capable of forming dielectric oxide layer.Niobium’s chemical properties are very similar to tantalum.On exposing niobium to air, an oxide layer is formed which is blue in colour.Niobium has only one stable isotope niobium-93.Niobium has quite high melting point but the density lower than refractory metals.Niobium has the greatest magnetic penetration depth of all elements.Niobium becomes a superconductor at cryogenic temperatures.The density of niobium is 8400 in S.I.Niobium is a light-grey, crystalline, and ductile transition metal.Niobium is said to be thirty-fourth most common element in the earth’s crust with concentration of 20 ppm. ![]() ![]() ![]() The difference between these two levels varies by element. The real truth is that the 4s and 3d subshells have nearly the same energy level. ![]() So, those also have to be learned on a case-by-case basis. Similar irregularities appear in the f block, only now there are s, d and f subshells all with similar energy levels. varies by element, we have to look at each element on a case-by-case basis to see how these will fill. In the d block it is the other way around.īecause the difference in energy levels between 4s-3d, 5s-4d, etc. The explanation is simple: in Groups 1 and 2, but not in the d block, the s is lower in energy than the d. there is the d to take into consideration. For the first few members to of Groups 1 and 2 there is no d to be filled. This leaves us with why you have s filling in Groups 1 and 2 instead of the d. And in palladium alone, the difference between d and s is so great that none of the electron are in the s. Sometimes the difference in energy levels between the s and d allows one electron to enter the s, sometimes it the difference allows 2 electrons to enter the s. The same process happens throughout the d-block. The difference in energy levels between 4s and 3d is small enough for the next two electrons to enter the 4s, because the electron-electron repulsion they feel if they enter 3d is enough to knock them into the 4s. ![]() So, with scandium, the first electron after completing the previous noble gas configuration goes into 3d. So, we have 3d and 4s co-filling rather than filling independently. However, because the 3d orbitals are smaller and more closely packed than the 4s, the electron-electron repulsion that occurs in the 3d subshell is enough to make it possible for 1 or 2 electrons to have a lower energy by occupying the 4s. In scandium and the other d block members of period 4, the 3d is lower in energy than the 4s. ![]() How much of a difference, and which subshell is lower in energy, varies by element. The 4s and 3d subshells have nearly the same energy level. I have assumed that the configuration that follows the rules is the ground state, since that is what is usually taught in general chemistry. Note: Nickel has two electron configurations that are commonly encountered over which there is a dispute amongst chemists as to which should be considered the ground state. There is a simple chart that makes learning the filling order easy. He did not know that La is an exception to the rule. Note: in one of his videos, Sal does the configuration of La, but he gets it wrong. However, it is unlikely you would be asked to know these in a general chemistry course. Thus, the actual configuration of the Pd is 4d¹⁰ (the 5s is empty).Īll the other exceptions are in the f block and just have to be learned on a case-by-case basis. Both of these electrons are instead in the outermost d subshell. In Pd (palladium) the outermost s subshell, predicted to have 2 electrons, is actually empty. In the following elements, there is 1 electron, not the predicted 2, in the outermost s subshell, the "missing" electron is instead located in the outermost d subshell: So, rather than going through the far more difficult to understand rules that do correctly predict the electron configurations for all elements, it is easier just to learn the elements that this simplified method doesn't work correctly for. There are similar irregularities in the filling of 5s and 4d as well as some other pairs of subshells. For example, the 4s and 3d have nearly the same energy level and so, in a way that varies according to which element it is, either of the two subshells could be the first to fill and there is no certainty that one will be completely filled before the other actually starts filling. The actual filling order is more complicated. This pattern will give you the correct configuration for all but about 19 elements. There are no known elements that, in their ground state, have electrons in a subshell beyond 7p. What you do is you start assigning electrons to the subshells using the following pattern (you completely fill up one subshell before moving onto the next higher) and you keep going until the total number of electrons assigned is equal to the atomic number:ġs, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p However, in the simplified version of these rules that is understandable to a general chemistry student, there are about 19 elements that are exceptions. Given the atomic number, there is a set of rules that allow you to determine the electron configuration. Without that, you cannot determine the electron configuration. You must know the atomic number of the element. ![]() ![]() Price adjustments apply only to purchase price and do not include taxes, shipping or other fees. Price adjustment will be provided in same manner as purchase method. For purchases from a Microsoft Experience Center, customer must return to the location with receipt. For purchases from Microsoft Store, contact Microsoft Store Sales and Support with your Microsoft Account information and any other information requested by a representative. Customer is eligible only if price of the purchased product is reduced during the Offer Period and in stock. Excludes Surface Hub, HoloLens, and Windows DevKit. Microsoft reserves the right to modify or discontinue offers at any time.Valid on purchases of physical products made at Microsoft Store online with a valid Microsoft Account and at Microsoft Experience Centers in select markets for 60 days from the date the customer receives the product (“Offer Period”). Microsoft reserves the right to modify or discontinue offers at any time. Promotional items given, or discounted products bought with, a qualifying product are not valid or must be returned if the qualifying product is returned. May not be combined with other offers. Applicable return policy applies to each purchase. Cannot be transferred or otherwise redeemed for cash or gift cards, or credit towards other devices or products. Customer must mail in the qualifying trade-in device to be eligible for the reimbursements. Device cannot be password protected, and must include original chargers/accessories, and must contain hard drive. To be eligible for trade in, you must own the qualifying device, device must power on, battery must hold charge and not be required to be plugged in to operate, and be in fully- functional, working condition without broken/missing components, cracked display/housing, liquid damage, modification(s) or have device warranty seal broken. Offer valid for reimbursements after trade in of qualifying devices (PC, laptop, mobile phone, tablet, video game console). Recycled devices are not eligible for cash back. Trade-In: Available only through the Microsoft Store online in Canada. Microsoft reserves the right to modify or discontinue offers at any time. For purchases made at a Microsoft Experience Center, see receipt for more information. For purchases made at Microsoft Store, see applicable Microsoft Terms of Sale for more information. Excludes Surface Hub, HoloLens, and Windows DevKit. ![]() Limit 5 product returns per eligible customer purchase. Return process must be started within 60 days after customer receives the product. Returns: Available with eligible physical products purchased from Microsoft Store online and Microsoft Experience Centers in select markets. See here for full terms and full list of eligible retailers. Limit 1 price adjustment total per product. For purchases from Microsoft Store, contact Microsoft Store Sales and Support with your Microsoft Account information and any other information requested by a representative. For purchases from a Microsoft Experience Center, you must return to the location with your receipt. Customer must contact Microsoft to request the adjustment. Customer is eligible only if the product is in stock for purchase at Microsoft Store or a Microsoft Experience Center. Both price adjustments: Price Adjustment must be requested within 60 days after the customer receives the product and cannot be completed at time of purchase. Microsoft reserves the right to verify an eligible retailer’s advertised price and availability of the product. The product sold by the eligible retailer must be identical to the product sold by Microsoft and must be in stock for purchase at the eligible retailer at the reduced price. An Eligible Retailer Price Adjustment cannot be requested at time of purchase. ![]() Excludes commercial and refurbished products. Eligible Retailer Price Adjustment: Valid on purchases of qualifying new consumer physical products from Microsoft Store and Microsoft Experience Centers in select markets for 60 days from the date product is received. Price protection: Microsoft Store Price Adjustment: Valid on purchases of qualifying new or refurbished consumer and commercial physical products made at Microsoft Store and Microsoft Experience Centers in select markets for 60 days from the date product is received. ![]() ![]() ![]() The re-sleeved Bancroft has no memories of the previous two days, including his own death. On Earth, a Meth named Laurens Bancroft has died in mysterious circumstances in Bay City (formerly San Francisco). Kovacs is sentenced to a long term in stack storage. On the colony planet of Harlan's World, Takeshi Kovacs and his partner Sarah Sachilowski, former Envoys who had returned to a life of crime, are killed by a U.N. Envoys are so successful and dangerous that they are generally prohibited from holding elected office on any world. They are an elite military group with extensive training in re-sleeving and psychological modification, as well as combat. In order to deal with the challenges of interspace warfare, the U.N. ![]() Numerous colony planets exist apart from Earth many were previously inhabited by an extinct alien civilization referred to as the Elders. Their consciousness is preserved and stored virtually, sometimes for decades, while their body is sold to the highest bidder to be used for re-sleeving another person. People who commit serious crimes are imprisoned "on stack". This ensures that even if their stack is destroyed, they can be re-sleeved. The very rich are also able to keep copies of their minds in remote storage, which they update regularly. Those who have lived for multiple lifespans are called Meths, a reference to the Biblical figure Methuselah. Only the wealthy are able to acquire replacement bodies on a continual basis. Thus, while people can live indefinitely in theory, most choose not to. While most people can afford to get resleeved at the end of their lives, they are unable to update their bodies and must go through the full aging process each time, which discourages most from re-sleeving more than once or twice. Dual-sleeving, or controlling two bodies with one personality, is strictly prohibited by U.N. This proposition reverses precedent and would allow authorities to temporarily re-sleeve a deceased Catholic woman to testify in a murder trial. At the start of the novel, UN Resolution 653 is being debated. This makes Catholics easy targets for murder, since killers know their victim may not be re-sleeved to testify. Roman Catholics do not allow their stacks to be re-sleeved after death, as they believe that the soul goes to Heaven when they die, and so would not pass on to the new sleeve. ![]() Their stacks can be downloaded into new bodies, or "sleeves", after death. If their body dies, their stack can be stored indefinitely. Most people have cortical stacks in their spinal columns that store their consciousness. In the future, humans have achieved virtual immortality. In 2019 a graphic novel was created with Dynamite Comics. ![]() The book was adapted as a Netflix television series, also titled Altered Carbon, in 2018. It is followed by the sequels Broken Angels and Woken Furies. elite soldier turned private investigator, to investigate a rich man's death. Set in a future in which interstellar travel and relative immortality is facilitated by transferring consciousnesses between bodies ("sleeves"), it follows the attempt of Takeshi Kovacs, a former U.N. Altered Carbon is a 2002 cyberpunk novel by the English writer Richard K. ![]() ![]() The ECO display informs you about the sustainability of your driving style. It also compares your fuel consumption with that of other drivers of the same vehicle model. In addition, you can configure Speedfencing and Valet Protect in the app, and receive push notifications in the event of their violations.įUEL-SAVING DRIVING: The Mercedes me App shows you your vehicle's individual fuel consumption. The Geofencing service sends you a notification as soon as the vehicle enters or leaves an area defined by you. ![]() If a vehicle alarm has been tripped, you can turn it off via the app. SAFETY IN AN EMERGENCY: The Mercedes me App notifies you of attempted theft, an attempt to tow away the vehicle and parking damage. This means you can get in and drive off straight away. In electric vehicles, you can also activate pre-entry climate control and temper the vehicle immediately or for a defined departure time.ĬONVENIENT ROUTE PLANNING: Plan your route at your leisure and conveniently send addresses to your Mercedes via the app. Start the auxiliary heating/ventilation or program this for your departure time. You can also pinpoint the location of your vehicle and receive warning messages regarding unlocked doors, for example.ĬONVENIENT VEHICLE CONTROL: With the Mercedes me App, you can remotely lock and unlock or open and close the doors, windows, and sliding sunroof. ![]() Use the app to conveniently check your tyre pressure, the status of the doors, windows, sliding sunroof/soft-top and boot, or the current locking status. You have an overview of all information and control your vehicle via the app.ĪLWAYS INFORMED: The Vehicle Status informs you about the mileage, range, current fuel level or data from your last journey, for example. Your smartphone becomes the digital link to your Mercedes. ![]() ![]() ![]() ![]() In February 2013, it was reported that Lloyds Banking Group was considering a stock market flotation of the TSB business as an alternative, should the transfer not be completed, and they would make a final decision by the end of July. The final transfer of TSB Bank to the new owner was planned to be completed by late 2013. Lloyds Banking Group reached a heads-of-terms agreement in July 2012 to sell the Verde branches to the Co-operative Bank for £750 million. Agreement with Co-operative Banking Group The remainder of the Lloyds TSB business was rebranded back to the Lloyds Bank name. A number of Lloyds TSB branches in England and Wales, together with all branches of Lloyds TSB Scotland and Cheltenham & Gloucester, were brought together to form the new business, which operates under the TSB brand. Customers with accounts held by the branches and staff employed within them were also transferred. Ĭodenamed "Verde", the group's divestment plan identified 632 branches which were transferred to a new business. In 2009, following the UK bank rescue package, the Government of the United Kingdom took a 43.4% stake in Lloyds Banking Group, which later announced that it would sell a standalone retail banking business of 632 branches and most accounts held at those branches in order to comply with European Commission state aid requirements. Lloyds TSB Group bought HBOS in January 2009 and renamed itself Lloyds Banking Group. Project Verde TSB Newcastle city centre, a former Lloyds TSB branch The parent, TSB Banking Group, was registered in England in 2014 and later that year TSB Bank ceased to be part of the Lloyds Banking Group. This company was re-registered under the name TSB Bank in 2013. In 1986, the legal entity, Trustee Savings Bank, was renamed TSB Scotland (and, in 1989, TSB Bank Scotland), before becoming Lloyds TSB Scotland in 1999. The original TSB Bank transferred engagements to Lloyds Bank which then changed its name to Lloyds TSB Bank at the same time, TSB Bank Scotland absorbed Lloyds' three Scottish branches becoming Lloyds TSB Scotland. The new bank commenced trading in 1999, after the statutory process of integration was completed. Lloyds Bank was delisted from the London Stock Exchange and TSB Group was renamed Lloyds TSB Group in 1995, with former Lloyds Bank shareholders owning a 70% equity interest in the share capital, effected through a scheme of arrangement. The merger was structured as a reverse takeover by TSB. The TSB name was previously used by the Trustee Savings Bank prior to its merger with Lloyds Bank in 1995, resulting in the formation of Lloyds TSB in 1999. In 2015, it was acquired by Sabadell Group. Post-divestment, TSB offered an initial public offering and was listed on the London Stock Exchange in June 2014. The bank was formed from the existing business of Lloyds TSB Scotland plc, into which a number of Lloyds TSB branches in England and Wales and all branches of Cheltenham & Gloucester were transferred, and renamed TSB Bank plc.Ī European Commission ruling that the British government's 2009 purchase of a 43% stake in Lloyds Banking Group counted as state aid made it necessary for Lloyds Banking Group to sell a portion of its business TSB was divested. Its headquarters are located in Edinburgh, Scotland, and it has more than five million customers with over £37 billion of lending and £36 billion of customer deposits. TSB Bank plc is a retail and commercial bank in the United Kingdom and a subsidiary of Sabadell Group.Īs at 2022, TSB Bank operates a network of 220 branches. ![]() ![]() ![]() This half-saxophone colossus is now a prominent member of the Anti-Skullgirls' Lab 8, and a father figure to the young soldiers. I expect to see a UN Owen Was Her? cover ASAP. Ben Birdland, aka Big Band in Skullgirls, is a former New Meridian cop turned into a cybernetic weapon by Dr. On the flip side, his large hurtbox leaves him vulnerable to instant overheads and stray hits. HI My name is Knuckles (knux), 22, im an artist, singer, vtuber model rigger, and content creator. Big Band has a variety of large moves that can control most of the screen, and has simple but effective mixup that leads to high damage. Here's a good one if you enable slow motion in training mode then record a song with your dummy, returning the game to normal speed and playing back your dummy will also speed up your recording! This enables you to play otherwise near-impossible songs on his trumpet by playing them in slow motion, then speeding them up by disabling slow motion. Big Band features the same stunning, feature-quality animation and great gameplay youve come to expect from Skullgirls and Lab Zero Games, as well as a story. Big Band used to be a cop, now he walks a different beat.Skullgirls dev s gorgeous hand drawn action platformer Indivisible out in. By using dummy recording in training mode, you can make a recording of your beautiful music by playing it through a training dummy! This can enable you to have a dummy play one half of a particularly difficult song while you perform the easy half live, or if you're feeling ballsy you can have a trumpet battle and play alongside your dummy. Big bang theorie filles nue Desabiller une femme nue sous hypnotiser. ![]() (1) dfgdhrg (2) Satchmo Solo Trolling with Big Band (Skullgirls Encore Character Guides) 1. The inputs, for the curious, are LK+MK, LK+MK, LK, LK+MK, HK, 8HP, 8HP, 8LP+HP. Big Band is a DLC Vermis (highlighted in red) on the cerebellum.
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